We will show that the quantitative maximal volume entropy rigidity holds on Alexandrov spaces. More precisely, given $N, D$, there exists $ε(N, D)>0$, such that for $ε<ε(N, D)$, if $X$ is an $N$-dimensional Alexandrov space with curvature $\geq -1$, $\operatorname{diam}(X)\leq D, h(X)\geq N-1-ε$, then $X$ is Gromov-Hausdorff close to a hyperbolic manifold. This result extends the quantitive maximal volume entropy rigidity of \cite{CRX} to Alexandrov spaces. And we will also give a quantitative m...