We investigate the construction of chaotic probability measures on the Boltzmann's sphere, which is the state space of the stochastic process of a many-particle system undergoing a dynamics preserving energy and momentum. Firstly, based on a version of the local Central Limit Theorem (or Berry-Esseen theorem), we construct a sequence of probabilities that is Kac chaotic and we prove a quantitative rate of convergence. Then, we investigate a stronger notion of chaos, namely entropic chaos introdu...