This paper introduces FourNet, a novel single-layer feed-forward neural network (FFNN) method designed to approximate transition densities for which closed-form expressions of their Fourier transforms, i.e. characteristic functions, are available. A unique feature of FourNet lies in its use of a Gaussian activation function, enabling exact Fourier and inverse Fourier transformations and drawing analogies with the Gaussian mixture model. We mathematically establish FourNet's capacity to approxima...